A Ru-bda Complex with a Dangling Carboxylate Group: Synthesis and Electrochemical Properties
نویسندگان
چکیده
منابع مشابه
a comparison of teachers and supervisors, with respect to teacher efficacy and reflection
supervisors play an undeniable role in training teachers, before starting their professional experience by preparing them, at the initial years of their teaching by checking their work within the proper framework, and later on during their teaching by assessing their progress. but surprisingly, exploring their attributes, professional demands, and qualifications has remained a neglected theme i...
15 صفحه اولBase-enhanced catalytic water oxidation by a carboxylate-bipyridine Ru(II) complex.
In aqueous solution above pH 2.4 with 4% (vol/vol) CH3CN, the complex [Ru(II)(bda)(isoq)2] (bda is 2,2'-bipyridine-6,6'-dicarboxylate; isoq is isoquinoline) exists as the open-arm chelate, [Ru(II)(CO2-bpy-CO2(-))(isoq)2(NCCH3)], as shown by (1)H and (13)C-NMR, X-ray crystallography, and pH titrations. Rates of water oxidation with the open-arm chelate are remarkably enhanced by added proton acc...
متن کاملSynthesis of a new dithiocarbamate cobalt complex and its nanoparticles with the study of their biological properties
Nano dithiocarbamate (DTC) complex have been prepared by reaction between dithiocarbamate and metal salt under ultrasound irradiation. Reaction conditions such as the ligand DTC and phennantroline concentration, aging time and the ultrasonic device power show important roles in the size, morphology and growth process of the final products. The dithiocarbamate complex nanoparticles have been pre...
متن کاملSynthesis of a new dithiocarbamate cobalt complex and its nanoparticles with the study of their biological properties
Nano dithiocarbamate (DTC) complex have been prepared by reaction between dithiocarbamate and metal salt under ultrasound irradiation. Reaction conditions such as the ligand DTC and phennantroline concentration, aging time and the ultrasonic device power show important roles in the size, morphology and growth process of the final products. The dithiocarbamate complex nanoparticles have been pre...
متن کاملRu(II) complexes with N-heterocyclic carbene ligands or terpyridine analogues: synthesis, characterization, and electrochemical and proton-dependent spectrometric properties.
Four ruthenium(II) complexes, BPT, BPN, BPPT, and BPPN, have been prepared and characterized by (1)H NMR, (13)C NMR, high resolution mass spectrometry (HRMS), elemental analysis, and X-ray crystallography. All the complexes incorporate a pyridyl unit on the terpyridine-type or N-heterocyclic carbene (NHC) ligand and the pyridyl unit can be protonated upon addition of 1.0 M HCl in diethyl ether....
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2020
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.9b03595